Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Self‐centering structural systems with combination of hysteretic and viscous energy dissipations

This paper presents an innovative set of high‐seismic‐resistant structural systems termed Advanced Flag‐Shaped (AFS) systems, where self‐centering elements are used with combinations of various alternative energy dissipation elements (hysteretic, viscous or visco‐elasto‐plastic) in series and/or in parallel. AFS systems is developed using the rationale of combining velocity‐dependent with displacement‐dependent energy dissipation for self‐centering systems, particularly to counteract near‐fault earthquakes. Non‐linear time‐history analyses (NLTHA) on a set of four single‐degree‐of‐freedom (SDOF) systems under a suite of 20 far‐field and 20 near‐fault ground motions are used to compare the seismic performance of AFS systems with the conventional systems. It is shown that AFS systems with a combination in parallel of hysteretic and viscous energy dissipations achieved greater performance in terms of the three performance indices. Furthermore, the use of friction slip in series of viscous energy dissipation is shown to limit the peak response acceleration and induced base‐shear. An extensive parametric analysis is carried out to investigate the influence of two design parameters, λ₁ and λ₂ on the response of SDOF AFS systems with initial periods ranging from 0.2 to 3.0 s and with various strength levels when subjected to far‐field and near‐fault earthquakes. For the design of self‐centering systems with combined hysteretic and viscous energy dissipation (AFS) systems, λ₁ is recommended to be in the range of 0.8–1.6 while λ₂ to be between 0.25 and 0.75 to ensure sufficient self‐centering and energy dissipation capacities, respectively. Copyright © 2010 John Wiley & Sons, Ltd.     

Shaking‐table tests of flat‐bottom circular silos containing grain‐like material

According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd.     

On the use of the autocorrelation function: the constraint of using frequency band-limited signals for monitoring relative velocity changes

Correlations of seismic noise are commonly used to monitor temporal variations of relative seismic velocity in period ranges from 1 s up to 100 s. Of particular interest is the detection of small changes in the order of 0.01–0.1 % in propagation speeds. Measuring such small differences can, however, be significantly biased by temporal variations in the properties of the noise sources within the corresponding frequency band. Using synthetic data, we show that apparent relative velocity variations might appear only due to changes in the amplitude and frequency content caused by source variations. Removing such unwanted effects by applying narrow bandpass filters in the preprocessing restricts the high-resolution analysis of any signal due to Gabor’s uncertainty limit, i.e., the correlation function suffers a limited resolution to time delay estimates for small correlation times, low-frequency ranges, and in narrow frequency bands. Better understanding of spatiotemporal noise source properties and the theoretical limitations of time–frequency analysis is critical for accurate and reliable passive monitoring.     

State-of-the art and future of earthquake early warning in the European region

European researchers and seismic networks are active in developing new approaches to earthquake early warning (EEW), implementing and operating test EEW systems, and in some cases, offering operational EEW to end users. We present the key recent developments in EEW research in Europe, describe the networks and regions where EEW is currently in testing or development, and highlight the two systems in Turkey and Romania that currently provide operational systems to a limited set of end users.     

Criteria of geographic relevance: an experimental study

The relevance of geographic information has become an emerging problem in geographic information science due to an enormous increase in volumes of data at high spatial, temporal, and semantic resolution, because of ever faster rates of new data capturing. At the same time, it is not clear whether the concept of relevance developed in information science and implemented for document-based information retrieval can be directly applied to this new, highly dynamic setting. In this study, we analyze the criteria users apply when judging the relevance of geographic entities in a given mobile usage context. Two different experiments have been set up in order to gather users' opinions on a set of possible criteria, and their relevance judgements in a given scenario. The importance ascribed to the criteria in both experiments clearly implies that a new concept of relevance is required when dealing with geographic entities instead of digital documents. This new concept of ‘Geographic Relevance’ is highly dependent on personal mobility and user's activity, whose understanding may in turn be refined by the assimilation of ‘Geographic Relevance’ itself.     

Shifts in isotopic signatures of animals with complex life-cycles can complicate conclusions on cross-boundary trophic links

Stable isotopes (¹³C and ¹⁵N) are widely applied in studies of trophic links. We used this method to investigate the contribution of aquatic and terrestrial prey to the diet of riparian predatory arthropods in two mountain headwater streams in Colorado, USA. Aquatic and terrestrial prey and riparian predators were collected during summer 2009. To evaluate the reliability of conclusions based on stable isotope ratios, we compared the isotopic signatures of aquatic larval and terrestrial adult stages of three abundant stream insect species and assessed variation in mixing model estimates for spider diet composition under varying assumptions for trophic fractionation. Adult isotopic signatures of some aquatic prey species were indistinguishable from those of prey species with exclusively terrestrial life histories (stoneflies: ¹³C and ¹⁵N, chironomids: ¹³C). Other prey had distinctly aquatic isotopic signatures as both larvae and adults (a mayfly and a caddisfly). There was no evidence that prey with aquatic isotopic signatures contributed to the diet of the spiders near one stream. For the other stream, mixing model analysis suggested that chironomids were included in the diets of lycosid, linyphiid and liocranid spiders. Reliable estimates of the contributions of prey sources were compromised by the sensitivity of mixing models to assumptions on trophic fractionation and the presence of “isotopically cryptic” prey. This study emphasizes the importance of supporting isotope-based studies on cross-boundary trophic links with data on isotopic shifts in prey with complex life cycles and assessment of fractionation rates specific to the study system.     

On the propagation of topographically trapped waves

Abstract

In the context of ageostrophic theory in a homogeneous ocean, a nondimensional number is determined which corresponds to the Ursell number for long gravity waves. It is defined as Q = NL ²/h ³, where N is the amplitude of the wave travelling along the long length-scale direction, L is its length and h (which for gravity waves is the water depth) is given by h=(l ⁴ f ²/g)^1/3. where l is the short length-scale, f the Coriolis parameter and g the acceleration due to gravity. The physical meaning of Q is as follows: if Q? O(1) the free evolution of the wave is linear and weakly dispersive, if Q = O(1) nonlinear and dispersive effects balance out and finally if Q ?O(1) the evolution is nonlinear and non-dispersive. Expressions for the time scales for the development of dispersive and nonlinear effects are also determined. These results apply to topographically trapped waves, namely barotropic continental shelf and double Kelvin waves travelling along a rectilinear topographic variation.